Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 616-43-3, is researched, Molecular C5H7N, about The synthesis of new 3-substituted pyrroles, the main research direction is silylpyrrole; pyrrole silyl; desilylation silylpyrrole.Category: chiral-oxygen-ligands.
The synthesis of 3-alkyl-, 3-(ω-bromoalkyl)-, 3-iodo-, 3-formyl-, 3-acetyl-1-(triisopropylsilyl)pyrrole, 2-[1-(triisopropylsilyl)-3-pyrrolyl]-2-propanol, 1-(triisopropylsilyl)-3-pyrrolecarboxylic acid, and 7-[1-(triisopropylsilyl)-3-pyrrolyl]heptanoic acid as well as the desilylation of these products to the corresponding 3-substituted pyrroles is described. Intermediates in these syntheses are 1-(triisopropylsilyl)pyrrole, 3-bromo-, and 3-litho-1-(triisopropylsilyl)pyrrole.
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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate