Related Products of 19132-06-0, Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction by binding to a specific portion of an enzyme and thus slowing or preventing a reaction from occurring. In a document type is Article, and a compound is mentioned, 19132-06-0, Name is (2S,3S)-Butane-2,3-diol, introducing its new discovery.
CHIRAL SYNTHESIS OF (2S,3S,7S)-3,7-DIMETHYLPENTADECAN-2-YL ACETATE AND PROPIONATE, POTENTIAL SEX PHEROMONE COMPONENTS OF THE PINE SAW-FLY NEODIPRION SERTIFER (GEOFF.)
A synthesis of (2S,3S,7S)-3,7-dimethylpentadecan-2-yl acetate (2) and propionate (3) is described. (2S)-2-Methyldecan-1-yl lithium (5) was reacted with (3S,4S)-3,4-dimethyl-gamma-butyrolactone (6) to yield the ketoalcohol 19 which upon Huang-Minlon reduction furnished (2S,3S,7S)-3,7-dimethylpentadecan-2-ol (1).Acylations gave the esters 2 and 3.The (2S)-2-methyldecan-1-yl lithium was obtained via asymmetric synthesis.The chiral lactone 6 was obtained from (2S,3S)-trans-2,3-epoxybutane and dimethylmalonate.
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Reference：
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate