Chemistry involves the study of all things chemical – chemical processes, chemical compositions and chemical manipulation – in order to better understand the way in which materials are structured, how they change and how they react in certain situations. name: (2S,3S)-Butane-2,3-diol,
Chiral induction has been achieved during a biomimetic cyclization of a chiral perillene derivatives in maximum 76percent diastereomeric excess.The absolute configuration of the predominant products are established by X-ray diffraction study and chemical transformations.
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Reference：
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate