In chemical reaction engineering, simulations are useful for investigating and optimizing a particular reaction process or system. Related Products of 4254-15-3,
(S)-(+)-Dermolactone 3 has been synthesised in monochiral form beginning with ethyl (S)-lactate, the tetracyclic nucleus being assembled by way of a regiospecific cycloaddition between the known chloronaphthoquinone 15 and the novel, highly functionalised chiral butadiene 5.Isochiral dermolactone 3 + 4 is prepared in the same way from (+/-)-5.Dermolactone, as it occurs naturally, is shown by 1H NMR shift experimants on the corresponding permethyl ethers 25 and 27, using
Related Products of 4254-15-3, Future efforts will undeniably focus on the diversification of the new catalytic transformations. These may comprise an expansion of the substrate scope from aromatic and heteroaromatic compounds to other hydrocarbons. Keep reading other articles of 4254-15-3!
Reference：
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate