New explortion of (S)-Butane-1,3-diol

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 24621-61-2. In my other articles, you can also check out more blogs about 24621-61-2

Reference of 24621-61-2, Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about Reference of 24621-61-2, Name is (S)-Butane-1,3-diol

Chiral alpha,omega-Dioxy-Carbanions from 1,3-Propanediol and 1,4-Butanediol by Sparteine-Assisted Deprotonation. Enantioselective Synthesis of 1,3- and 1,4-Diols, (R)-Pantolactone, and a Cyclopropane

Prostereogenic mono- and dicarbamates of 1,3-propanediol and 1,4-butanediol are deprotonated by the sec-butyllithium/(-)-sparteine system with high enantiotopic differentiation.The electrophilic substitution of the intermediate chiral carbanions furnishes the title compounds with >95percent ee. Key words: Chiral 1-oxy-carbanions; enantioselective deprotonation; (-)-sparteine.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Reference of 24621-61-2. In my other articles, you can also check out more blogs about 24621-61-2

Reference£º
Synthesis and Crystal Structure of a Chiral?C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur¨Cnitrogen¨Coxygen ligand derived from aminothiourea and sodium?D-camphor-¦Â-sulfonate