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We report the syntheses and crystal structures of novel organotin chloride complexes with functional organic substituents from HSnCl3· 2Et2O (1-3). Whereas Cl3SnCHPhCH2C(O)(CH) 2Ph (1) was synthesized in a traditional route from HSnCl 3·2Et2O and dibenzylideneacetone, C 6H5Cl5O4Sn2 (2) and C8H9Cl5O4Sn2 (3) represent products of a condensation reaction of mononuclear organotintrichlorides that comprise both C=C and C=O functional groups and additionally exhibit characteristic intramolecular donor-acceptor interactions. Due to the condensation, compounds 2 and 3 combine SnCl2 with SnCl3 groups within one molecule. Copyright
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Reference：
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate