Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like SDS of cas: 19132-06-0, Name is (2S,3S)-Butane-2,3-diol. In a document type is Article, introducing its new discovery., SDS of cas: 19132-06-0
Syntheses of chiral hybrid O,N-donor ligands for the investigation of lanthanide complex reactivities in direct aldol condensations
A method for the synthesis of new chiral alpha/beta-dimethylamino esters and beta-amino ethers from (S,S)-hydrobenzoin is described. These new O,N-donor ligands are expected to prove a useful platform for exploring the relationship between the ligand structure and stereoselective direct aldol condensation catalyzed by their lanthanide complexes. The initial survey of the catalytic utility of newly synthesized complexes in the unique aldol-Tishchenko reaction of aldehydes and aliphatic ketones is also presented.
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Reference£º
Synthesis and Crystal Structure of a Chiral?C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur¨Cnitrogen¨Coxygen ligand derived from aminothiourea and sodium?D-camphor-¦Â-sulfonate