The molecularity of an elementary reaction is the number of molecules that collide during that step in the mechanism. If there is only a single reactant molecule in an elementary reaction, that step is designated as unimolecular.538-58-9, name is 1,5-Diphenylpenta-1,4-dien-3-one. A new synthetic method of this compound is introduced below. , 538-58-9
General procedure: To a solution of DVK 1 (0.2 mmol) and active methylene 2 (0.24 mmol) was addedt-Bu-P2 (10uL, 10 mol%) via a micro syringe at room temperature. The reactionmixture was stirred for 2-24 h as indicated in Table 2. The solvent was then removedin vacuo and the crude product was purified by flash chromatography on silica gel(PE/EA = 15:1-10:1) to give the desired product 3.
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Reference£º
Article; Li, Yang-Guo; Zhang, Yang; Du, Guang-Fen; Gu, Cheng-Zhi; He, Lin; Letters in Organic Chemistry; vol. 16; 1; (2019); p. 76 – 80;,
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