Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 56413-95-7, is researched, SMILESS is N#CC1=NC(Cl)=C(Cl)N=C1C#N, Molecular C6Cl2N4Journal, European Journal of Inorganic Chemistry called A novel nickel(II) complex adopting a cis-configuration: solvothermal synthesis and crystal structure of [NiL2(H2O)4] (L = 1,4-dihydropyrazine-2,3-dione-5,6-dicarboxylate), Author is Liu, Cai-Ming; Zhang, De-Qing; Qin, An-Jun; Ye, Chen; Hu, Huai-Ming; Zhu, Dao-Ben, the main research direction is nickel pyrazinedionedicarboxylate complex preparation structure; crystal structure nickel pyrazinedionedicarboxylate complex; pyrazinedicarbodinitrile reaction cadmium nickel perchlorate hydrate.Application In Synthesis of 5,6-Dichloropyrazine-2,3-dicarbonitrile.
Under solvothermal reaction conditions, the reaction of 5,6-dichloropyrazine-2,3-dicarbonitrile and [Ni(ClO4)2]·6H2O produces a novel cis-Ni(II) complex [NiL2(H2O)4] (1) (L = 1,4-dihydropyrazine-2,3-dione-5,6-dicarboxylate), whereas only hydrated 1,4-dihydropyrazine-2,3-dione-5,6-dicarboxylic acid (2) was obtained as a single phase when [Cd(ClO4)2]·6H2O was used instead of [Ni(ClO4)2]·6H2O. The crystal structure of 1 was determined
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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate