So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Groves, J. K.; Anderson, Hugh J.; Nagy, H. researched the compound: 3-Methyl-1H-pyrrole( cas:616-43-3 ).Product Details of 616-43-3.They published the article 《Pyrrole chemistry. XIII. New syntheses of 3-alkylpyrroles》 about this compound( cas:616-43-3 ) in Canadian Journal of Chemistry. Keywords: pyrrole alkyl preparation. We’ll tell you more about this compound (cas:616-43-3).
3-n-Alkylpyrroles are prepared in good yield by a combined Wolff-Kishner reduction and hydrolysis and decarboxylation of 4-acyl-2-pyrrole-thiolcarboxylates. Me 4-isopropyl-2-pyrrolecarboxylate and 4-tert-butyl-2-pyrrolecarbonitrile are prepared by alkylation of Me 2-pyrrolecarboxylate and 2-pyrrolecarbonitrile, resp. Hydrolysis and decarboxylation of these disubstituted compounds afford the corresponding-3-alkylpyrroles. Mass spectral data for some 1-, 2-, and 3-alkylpyrroles are reported.
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Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate