This type of reactivity has quickly become one of the cornerstones of modern catalysis .In a patent, Recommanded Product: 538-58-9, name is 1,5-Diphenylpenta-1,4-dien-3-one, belongs to chiral-oxygen-ligands compound, introducing its new discovery. Recommanded Product: 538-58-9
Fe-catalyzed dithiane radical induced C?S bond activation?addition to alpha, beta-unsaturated ketones
An efficient and clean strategy to construct organosulfur compounds has been developed via a Fe-catalyzed dithiane C?S bond activation/addition process with alpha, beta-unsaturated ketones. This C?S activation protocol exhibits excellent reactivities, and up to 92% yield of the corresponding thioether-thioester derivatives could be obtained under the mild conditions, allowing the ready preparation of a number of synthetically valuable S-linked conjugates. (Figure presented.).
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Reference：
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate