19132-06-0, Name is (2S,3S)-Butane-2,3-diol, belongs to chiral-oxygen-ligands compound, is a common compound. 19132-06-0In an article, authors is Aoki, Shin, once mentioned the new application about 19132-06-0.
SIMPLE CHIRAL CROWN ETHERS COMPLEXED WITH POTASSIUM TERT-BUTOXIDE AS EFFICIENT CATALYSTS FOR ASYMMETRIC MICHAEL ADDITIONS
Simple C2-symmetric chiral crown ether 1 complexed with KOtBu was found to work as an efficient chiral catalyst in Michael additions to cause high asymmetric induction.The results with various chiral crown ethers as catalysts suggest that diaxial-like conformation of the vicinal methyl groups of 1<*>potassium enolate complex is responsible for the chiral induction.
Do you like my blog? If you like, you can also browse other articles about this kind. 19132-06-0Thanks for taking the time to read the blog about 19132-06-0
Reference£º
Synthesis and Crystal Structure of a Chiral?C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur¨Cnitrogen¨Coxygen ligand derived from aminothiourea and sodium?D-camphor-¦Â-sulfonate