Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3685-23-2, is researched, SMILESS is N[C@H]1CC[C@H](CC1)C(O)=O, Molecular C7H13NO2Journal, Journal of Organic Chemistry called Reductive cyclization of aminobenzoic acids, Author is Augustine, Robert L.; Vag, Linda A., the main research direction is aminobenzoic acid hydrogenation; cyclization reductive aminobenzoic acid; azabicyclooctanone; bicyclic lactam; bicyclic lactam.Recommanded Product: 3685-23-2.
Hydrogenation of m- and p-H2NC6H4CO2H over a Ru catalyst at 150°/1600 psig gave the bicyclic lactams I and II, resp. Cyclization also occurred on hydrogenation of 3,4-Me(H2N)C6H3CO2H. Hydrogenation of 3,4-(H2N)2C6H3CO2H resulted in loss of one of the NH2 groups; the 4-NH2 group was lost twice as readily as the 3-NH2 group. With 3,4-(HO)(H2N)C6H3CO2H, complete hydrogenolysis of the NH2 group occured.
In some applications, this compound(3685-23-2)Recommanded Product: 3685-23-2 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate