This type of reactivity has quickly become one of the cornerstones of modern catalysis .In a patent, Application In Synthesis of (S)-Butane-1,3-diol, name is (S)-Butane-1,3-diol, belongs to chiral-oxygen-ligands compound, introducing its new discovery. Application In Synthesis of (S)-Butane-1,3-diol
Ruthenium complexes of phosphinoferrocenylaminophosphine ligands (BoPhoz ligands) have been prepared by combining the ligands with tris(triphenylphosphine)ruthenium dichloride and precipitating the complexes. The optimal species exhibit high enantioselectivities for the asymmetric hydrogenation of functionalized ketones, particularly beta-ketoesters.
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Reference：
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate