Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 3685-23-2, is researched, Molecular C7H13NO2, about Hydrogenation of ammonium p-aminobenzoate on ruthenium and rhodium catalysts, the main research direction is catalytic hydrogenation ammonium aminobenzoate; benzoate amino ammonium hydrogenation; ruthenium catalysis aminobenzoate hydrogenation; rhodium catalysis aminobenzoate hydrogenation.Product Details of 3685-23-2.
The rate of hydrogenation of aqueous p-H2NC6H4CO2- NH4+ in the presence of 10% Rh/C exceeded that in the presence of 10% Ru/C or 9.5% Ru-0.5% Pd/C, and increased linearly with the pressure at 40-100 atm; the apparent activitation energy at 80-150° was 9-10 kcal/mole. The combined yield of cis- (I) and trans-4-amino-1-cyclohexanecarboxylic acid (II) was 92-3% at 80° and 80 atm, but decreased with increasing temperature owing to thermal decomposition; the II-I ratio was independent of pressure, but increased with the hydrogenation temperature, owing to cis-trans isomerization.
This literature about this compound(3685-23-2)Product Details of 3685-23-2has given us a lot of inspiration, and I hope that the research on this compound(cis-4-Aminocyclohexane carboxylic acid) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate