The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 3-Methyl-1H-pyrrole(SMILESS: CC1=CNC=C1,cas:616-43-3) is researched.SDS of cas: 3235-67-4. The article 《On the mechanism of the sensitized photooxygenation of pyrroles》 in relation to this compound, is published in Journal of the American Chemical Society. Let’s take a look at the latest research on this compound (cas:616-43-3).
The mechanism of dye-sensitized photooxygenation reaction of pyrrole, its N-methyl, 2-methyl, 3-methyl, and N-phenyl derivatives as well as kryptopyrrole, was studied at low temperatures via 1H-NMR spectral data and H218O in various solvents. Endo-peroxide intermediates (I) undergo rapid ground-state reactions, leading to 5-hydroxy-Δ3- pyrrolinones by two mechanisms: internal rearrangement and reaction with water.
There is still a lot of research devoted to this compound(SMILES：CC1=CNC=C1)SDS of cas: 616-43-3, and with the development of science, more effects of this compound(616-43-3) can be discovered.
Reference:
Synthesis and Crystal Structure of a Chiral C3-Symmetric Oxygen Tripodal Ligand and Its Applications to Asymmetric Catalysis,
Chiral lanthanide(III) complexes of sulphur–nitrogen–oxygen ligand derived from aminothiourea and sodium D-camphor-β-sulfonate